Synthesis of [9, 10-dihydro-9-(4-methylaminobutyl)-9, 10-propanoanthracene] using Diels–Alder cycloaddition
نویسندگان
چکیده
منابع مشابه
3 , 4 - Dihydroxy - 9 , 10 - secoandrosta - l , 3 , 5 ( 10 ) - triene = 9 , 17 dione 4 ,
Kinetic studies with 3,4-dihydroxy-9, IO-secoandrosta1,3,5(10)-triene-9,17-dione-4,5-dioxygenase gave intersecting initial velocity plots that conform to a sequential mechanism. Linear noncompetitive product inhibition patterns were observed with respect to either substrate, indicating the formation of a dead end complex. 4-Isopropyl catechol, a structural analogue of the organic substrate, inh...
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In the crystal structure of the title compound, C(27)H(20)NO(2) (+)·CF(3)SO(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems [centroid-centroid distances = 3.668 (2)-3.994 (2) Å]. These dimers are further linked by C-H⋯O and C-H⋯π inter-actions. The cation and the anion are connected by C-H⋯O inter-actions. The mean plane of the acridine ring...
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In the crystal of the title compound, C(21)H(15)ClNO(2) (+)·CF(3)SO(3) (-), adjacent cations are linked through C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.987 (2) Å], and neighboring cations and anions via C-H⋯O and C-F⋯π inter-actions. The acridine ring system and benzene ring are oriented at a dihedral angle of 1.0 (1)° while the carboxyl group is twisted at an angle of 85.0 ...
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In the title compound, C(22)H(16)O, the six-membered ring within the anthrone moiety adopts a shallow boat conformation, with puckering parameters Q = 0.2860 (17) Å, Θ = 99.1 (3)° and Φ = 114.8 (3)°. The dihedral angle between the outer benzene rings is 26.53 (8)°. The mean plane through the anthrone ring system makes a dihedral angle of 38.73 (6)° with the pendant benzene ring. In the crystal,...
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ژورنال
عنوان ژورنال: Journal of Saudi Chemical Society
سال: 2016
ISSN: 1319-6103
DOI: 10.1016/j.jscs.2013.03.001